Your WDC_WD20EZBX is an SMR drive which is not suited for ZFS and might well be the cause of your performance degradation. If this is a new NAS with no critical data on it (yet), you might want to just offline that drive (zpool offline <poolname> <diskid>
) and repeat your benchmarks. If that solves the problem replace the drive with a CMR one or create a new pool with one drive less.
You will lose redundancy when offlining the drive, so don't do this if there is valuable data on the pool. In that case you should definitely replace that drive.